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Investigations were conducted using mass blends of Iso-Paraffinic Kerosene (IPK) and Fischer-Tropsch Synthetic Kerosene (S8) to produce a synthetic surrogate for aerospace F-24. Due to the fossil fuel origin of F-24, the introduction of a synthetic surrogate would create a sustainable aviation fuel (SAF) with sources obtained from within the United States. An analysis of ignition delay (ID), combustion delay (CD), derived cetane number (DCN), negative temperature coefficient (NTC) region, Low-Temperature Heat Release region (LTHR) and High-Temperature Heat Release (HTHR) was conducted using a PAC CID 510 Constant Volume Combustion Chamber (CVCC). The fuels examined in this study are neat IPK, neat S8, neat F-24, and by mass percentages, as follows: 75IPK 25S8, 52IPK 48S8, 51IPK 49S8, 50IPK 50S8 and 25IPK 75S8. The DCN values determined for IPK, S8, and F-24 were 26.92, 59.56 and 44.35 respectively. The influence of IPK present in the blends increases CD, thus reducing the DCN significantly. The fuel blend of 50IPK 50S8 was observed to be the closest match to F-24 when comparing DCN, ID and CD. The surrogate blends were determined to have a lower magnitude of peak pressure ringing compared to that of the neat S8 and F-24, this is due to the extended NTC region caused by the IPK present in the blend. During further refinement of the surrogate blend, the Apparent Heat Release Rate (AHRR) curve for the 51IPK 49S8 fuel blend was found to have the closest match to the AHRR of F24. The surrogate blend 50IPK 50S8 was shown to have the smallest percent difference and best match during the LTHR stage, compared to F-24, while 52IPK 48S8 had the smallest percent difference for the energy released during LTHR. The ID and CD of the 25/75% blends were too dissimilar from the F-24 target to be considered as a surrogate. A Noise Vibration Harshness (NVH) analysis was also conducted during the combustion of the three neat fuels in the CVCC. This analysis was conducted to relate the ID, CD, HTHR and ringing to the vibrations that occur during combustion. Neat S8 was observed to have the most vibrations occurring during the combustion process. Additionally, the HTHR was observed to have a distinct pattern for the three neat fuels and the combustion of these fuels was quieter overall. 

In this study, iso-paraffinic kerosene (IPK) was analyzed for ignition delay, combustion delay, pressure trace, pressure rise rate and, apparent heat release rate in an experimental single cylinder indirect injection (IDI) compression ignition engine as well as in a constant volume combustion chamber (CVCC). Neat IPK, neat ULSD, and a by-mass blend of 50%IPK50%ULSD were analyzed in a CVCC and an IDI engine to determine the effect of Derived Cetane Number (DCN), Ignition Delay (ID), and Low Temperature Heat Release (LTHR) on combustion timing and engine knock. In the CVCC, IPK was found to have a significantly lower DCN than ULSD at 26 and 47, respectively. The blend was found to have a DCN between the two neat fuels at 37.5. Additionally, the ignition delay increased in the CVCC from 3.56 ms for ULSD to 5.3 ms for IPK with the blend falling between the two at 4.38 ms. For engine research, the single-cylinder experimental IDI engine was run at 2400 rpm at 5, 6, and 7 Indicated Mean Effective Pressure (IMEP) using each of the three researched fuels. It was found that when running neat IPK, there was a profound level of engine knock at all loads characterized by the 60% increase in the Peak Pressure Rise Rate (PPRR) when compared to ULSD. The pressure trace for IPK at all loads showed a significant delay in combustion due to IPK’s resistance to autoignition. This was observed in the increasing ignition delay in the engine from 0.88 ms for ULSD to 1.1 ms at 7 bar IMEP for IPK. Despite the delay in ignition for IPK, all three researched fuels reached peak Apparent Heat Release Rate (AHRR) at approximately 370° leading to a much more rapid increase in AHRR for IPK when compared to ULSD. This steep slope in the AHRR, also seen in the increased PPRR, and longer ID caused the high levels of engine knock, observed as oscillations in the pressure trace which decreased in magnitude as IMEP increased. 

Research was conducted to determine combustion characteristics such as: ignition delay (ID), combustion delay (CD), combustion phasing (CA 50), combustion duration, derived cetane number (DCN) and ringing intensity (RI) of F24, for its compatibility in Common Rail Direct Injection (CRDI) compression ignition (CI) engine. The first part of this study is investigating the performance of Jet-A, F24, and ultra-low sulfur diesel #2 (ULSD) using a constant volume combustion chamber (CVCC) followed by experiments in a fired CRDI research engine. Investigations of the spray atomization and droplet size distribution of the neat fuels were conducted with a Malvern Mie scattering He-Ne laser. It was found that the average Sauter Mean Diameter (SMD) for Jet-A and F24 are similar, with both fuels SMD droplet range between 25–29 micrometers. Meanwhile, ULSD was found to have a larger SMD particle size in the range of 34–40 micrometers. It was observed during the study, utilizing the CVCC, that the ID and CD for neat ULSD and Jet-A are nearly identical while the combustion of F24 is delayed. F24 was found to have longer durations of both ID and CD by approx. 0.5 ms. This results in a lower DCN for the fuel of 43.5, whereas ULSD and Jet-A have DCNs of 45 and 47 respectively. The peak AHRR for ULSD and Jet-A are nearly identical, whereas F24 has a peak magnitude of approx. 20% lower than ULSD and Jet-A. It was found that both aviation fuels had significantly fewer ringing events occurring after peak high temperature heat release (HTHR), a trend also observed in the CRDI research engine. Neat F24, Jet-A and ULSD were researched in the experimental engine at the same thermodynamic parameters: 5 bar indicated mean effective pressure (IMEP), 50°C (supercharged and EGR) inlet air temperature, 1500 RPM, start of injection (SOI) 16°BTDC, and 800 bar of fuel rail injection pressure as the baseline parameters in order to observe their ignition behavior, low temperature heat release, combustion phasing, and combustion duration. It was found that the ignition delay of F24 and Jet-A was greater than ULSD, approx. 5% for both aviation fuels. This ignition delay also affected the combustion phasing, or CA 50, of the aviation fuels. The CA 50 of the aviation fuels was delayed by approx. 2% compared to ULSD. Jet-A had a nearly identical combustion duration compared to ULSD, however F24 had an extended combustion duration which was approx. 3% longer than that of ULSD and Jet-A. It was discovered with the accumulations of these delays in ID, CD, CA50, that the RI of the aviation fuels were reduced. F24 was discovered to have more delays, and the RI correlates with these results having a 70% reduction in RI compared to ULSD.